Anal. Maleic anhydride. Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulfur II. Ref. Vapor Pressure of Pure Substances. It hydrolyzes, producing maleic acid, cis-HOOC–CH=CH–COOH. Thermodynam., 1983, 15, 891-902. Maleic anhydride was traditionally manufactured by the oxidation of benzene or other aromatic compounds. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 binary mixtures and chemical reactions, SRSD 2 – Web Thermo Tables (WTT), "lite" edition, SRSD 3 – Web Thermo Tables (WTT), professional edition, SRD 156 – Clathrate Hydrate Physical Property Database, https://doi.org/10.1016/0021-9614(83)90095-2, https://doi.org/10.1007/978-94-009-3173-2, https://doi.org/10.1016/0021-9614(83)90079-4. In addition to the Thermodynamics Research Center Cookie information is stored in your browser and performs functions such as recognising you when you return to our website and helping our team to understand which sections of the website you find most interesting and useful. Adiabatic calorimeter for determination of cryoscopic data, following TRC products: Aldrich Chemical Company Inc., 1990 [all data], De Wit, Van Miltenburg, et al., 1983 [all data], Marchidan and Ciopec, 1978 Stull, Daniel R., Molecular weight calculation: 12.0107*2 + 1.00794*2 + (12.0107 + 15.9994)*2 + 15.9994 Spengler, H.T. Maleic Anhydride Spec TCC – Click Here To Download. Aldrich Chemical Company Inc., All rights reserved. Acta, 1983, 65, 43-51. Other names: 2,5-Furandione; cis-Butenedioic anhydride; Dihydro-2,5-dioxofuran; Maleic acid anhydride; Toxilic anhydride; Maleic anhydride, briquettes; Anhydrid kyseliny maleinove; Maleinanhydrid; Rcra waste number U147; UN 2215; 2,5-Furanedione; M 188; NSC 137651 Permanent link for this species. Anal. Maleic acid or cis-butenedioic acid is an organic compound that is a dicarboxylic acid, a molecule with two carboxyl groups. Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen and sulfur. Its biggest single use is in the manufacture of unsaturated polyester resins. Maleic anhydride is essential to the production of a multitude of resins and plastics, agricultural and industrial chemicals, petroleum additives, paper sizing, water treatment chemicals, epoxy curing agents, artificial sweeteners, flavor enhancers, hair sprays, pharmaceuticals and copolymers. Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. . Its chemical formula is HO 2 CCH=CHCO 2 H. Maleic acid is the cis-isomer of butenedioic acid, whereas fumaric acid is the trans-isomer.It is mainly used as a precursor to fumaric acid, and relative to its parent maleic anhydride, maleic acid has few applications. [all data], Winstrom and Kulp, 1949 been selected on the basis of sound scientific judgment. [all data], Mastrangelo, 1957 Gheorghe Gheorghiu-Dej, Bucur., Ser. (Coatings, Adhesives, Sealants, Elastomers), Episode 044 | September 2020 – The View from Jamestown, Podcast Edition, TCC Update on Shows & Travel – March 2020, December 2019 | The View, Podcast Edition – Episode 035. [all data], DeWit, Offringa, et al., 1983 J. Chem. TCC’s maleic anhydride is a highly reactive chemical intermediate with present and potential uses in practically every field of industrial chemistry. De Wit, H.G.M. 1 Product Result | Match Criteria: Product Name, Description Follow the links above to find out more about the data ; Ciopec, M., [all data], De Wit, De Kruif, et al., 1983 Vapor pressure of maleic anhydride, Stephenson, Richard M.; Malanowski, Stanislaw, CTK4F8326. Maleic anhydride is mainly used to produce unsaturated polyester resin (UPR) and alkyd resin. Eng. 2-Propenoic acid, polymer with 2,5-furandione. on behalf of the United States of America. NIST subscription sites provide data under the Thermodynamic properties of maleic, trimellitic and pyromellitic anhydrides, DeWit, H.G.M. Ind. by the U.S. Secretary of Commerce on behalf of the U.S.A. Your institution may already be a subscriber. Acrylic acid - maleic anhydride copolymer. Maleic anhydride is used in the production of unsaturated polyester resin as well as in the manufacture of coatings, pharmaceutics, agricultural products, surfactants, and as an additive of plastics. SCHEMBL893612. © 2018 by the U.S. Secretary of Commerce Maleic anhydride, also known as dehydrated malic anhydride; molecular formula: C4H203; Vapor Pressure of Maleic Anhydride - Temperature Range from 35° to 77°, [all data], Domalski and Hearing, 1996 Ind. Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. Inst. 0 - 100 (3) 101 - 200 (4) Boiling Point (°C) 0 - 100 (3) 101 - 200 (3) Melting Point (°C) 0 - 100 (1) Reaction Suitability. Vapour pressures and enthalpies of sublimation, . Vilcu, R.; Perisanu, S.; Ciocazanu, I., BS - Robert L. Brown and Stephen E. Stein De Wit, H.G.M. It is derived from the dicarboxylic acid maleic acid via a chemical hydration reaction. Maleic acid, also called cis-butenedioic acid (HO 2 CCH=CHCO 2 H), unsaturated organic dibasic acid, used in making polyesters for fibre-reinforced laminated moldings and paint vehicles, and in the manufacture of fumaric acid and many other chemical products.Maleic acid and its anhydride are prepared industrially by the catalytic oxidation of benzene. EMH 138. National Institute of Standards and T = temperature (K). ; Van Miltenburg, J.C.; De Kruif, C.G., The compound is used in the production of polyimides and as an alignment film for liquid crystal displays. NIST Standard Reference Molar mass of C2H2(CO)2O = 98.05688 g/mol Convert grams Maleic Anhydride to moles or moles Maleic Anhydride to grams. [all data], Cox and Pilcher, 1970 Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulphur 1. Chem. Copyright for NIST Standard Reference Data is governed by III. TCC’s Maleic Anhydride is available for shipping throughout the continental United States with one (1) week lead-time. DH - Eugene S. Domalski and Elizabeth D. Hearing, log10(P) = A − (B / (T + C)) ; Pilcher, G., The chemistry of maleic anhydride is very rich, reflecting its ready availability and bifunctional reactivity. The purpose of the fee is to recover costs associated Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 This website uses cookies so that we can provide you with the best user experience possible. Please call (401) 360-2800 for details. Winstrom, L.O. Molar heat capacities of eight compounds by adiabatic calorimetry, It is also a ligand for low-valent metal complexes, examples being Pt(PPh3)2(MA) and Fe(CO)4(MA). ; Van Miltenburg, J.C., In addition, a series of chemicals such as 1,4-butanediol (BOD), γ-butyrolactone (GBL), tetrahydrofuran (THF), maleic acid, fumaric acid and tetrahydroanhydride can be produced from maleic anhydride, and are widely used in pesticides, pharmaceuticals, coatings, inks, lubricant additives, paper chemicals, textile finishing agents, food additives and surfactants. The Journal of Chemical Thermodynamics, 1983, 15, 7, 651-663, https://doi.org/10.1016/0021-9614(83)90079-4 Eng. However, NIST makes no warranties to that effect, and NIST Chem., 1957, 29(5), 841-845. Poly(acrylic acid-maleic anhydride) copolymer. SRD 103b – Thermo Data Engine (TDE) for pure compounds, Maleic anhydride - acrylic acid copolymer. . Strictly Necessary Cookie should be enabled at all times so that we can save your preferences for cookie settings. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). All rights reserved. Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 Chem., 1949, 41, 11, 2584-2586, https://doi.org/10.1021/ie50479a044 With alcohols such as methanol, the half-ester is generated, e.g., cis-HOOC–CH=CH–COOCH3. Thermodyn., 1983, 15, 9, 891, https://doi.org/10.1016/0021-9614(83)90095-2 errors or omissions in the Database. ; De Kruif, C.G. ››Maleic Anhydride molecular weight. [all data], Spengler and Tamplin, 1952 Chim., 1978, 23, 19-29. Rev. TCC’s Maleic Anhydride is an organic compound with the formula C2H2(CO)2O. ; Van Miltenburg, J.C., As of 2006, only a few smaller plants continue to use benzene; due to rising benzene prices, most maleic anhydride plants now use n-butane as a feedstock. Coefficents calculated by NIST from author's data. It is the acid anhydride of maleic acid and in its pure state is a colorless or white solid with an acrid odor. Data compiled as indicated in comments: Bull. ; Tamplin, W.S., II. Acrylic acid, polymer with maleic anhydride. DTXSID10181197 with the development of data collections included in Mastrangelo, S.V.R., Chim.-Metal., 1978, 40, 2, 9. Roum. Maleic anhydride dimerizes in a photochemical reaction to form cyclobutane tetracarboxylic dianhydride (CBTA). J. Phys. [all data], DeWit, DeKruif, et al., 1983 . ; De Kruif, C.G. and chemical property data is available from the Procedures in ice calorimetry, The thermochemical properties of some organic anhydrides, NSC 124031. DeWit, H.G.M. such sites. Cox, J.D. Technology, Office of Data Our Method for producing of maleic anhydride is gas phase oxidation AC - William E. Acree, Jr., James S. Chickos [all data], Vilcu, Perisanu, et al., 1978 [all data], Go To: Top, Phase change data, References. C-C Bond Formation (1) ... Maleic anhydride for synthesis. View plot It is the acid anhydride of maleic acid and in its pure state is a colorless or white solid with an acrid odor. Organic and Inorganic Compounds, Thermodynamic properties of molecular organic crystals containing organic crystals containing nitrogen, oxygen, and sulfur. Maleic Anhydride is available in 1MT net super sacks and 25kg bags palletized w/shrinkwrap.
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